[1]王 壮,张 威,蒋 妍,等. 锰基普鲁士蓝正极材料掺杂Fe2+的储钠性能研究[J].湖北工业大学学报,2022,(4):71-74.
　WANG Zhuang,ZHANG Wei,JIANG Yan,et al. Study on Sodium Storage Properties of Manganese Based Prussian ]Blue Cathode Materials Doped with Fe2+[J].,2022,(4):71-74.
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 锰基普鲁士蓝正极材料掺杂Fe2+的储钠性能研究()
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《湖北工业大学学报》[ISSN:1003-4684/CN:42-1752/Z]

卷:
期数:
2022年第4期
页码:
71-74
栏目:
湖北工业大学学报
出版日期:
2022-08-28

文章信息/Info

Title:
 Study on Sodium Storage Properties of Manganese Based Prussian ]Blue Cathode Materials Doped with Fe2+
文章编号:
1003-4684(2022)04-0071-04
作者:
 王 壮1;  张 威2;  蒋 妍2;  刘 昭1
 1 湖北工业大学电气与电子工程学院, 湖北 武汉 430068；
 2 湖北工业大学理学院， 湖北 武汉 430068
Author(s):
 WANG Zhuang1;  ZHANG Wei2;  JIANG Yan2;  LIU Zhao1
 1 School of Electrical and Electronic Engin., Hubei Univ. of Tech., Wuhan 430072, China;
 2 School of Science, Hubei University of Technology, Wuhan 430072, China
关键词:
 ; 钠离子电池;  普鲁士蓝;  共沉淀;  电化学;  正极材料
Keywords:
 ; sodium ion battery; Prussian blue; co-precipitation; electrochemical; cathode material
分类号:
TM92, O646
文献标志码:
A
摘要:
 以开放框架结构的普鲁士蓝材料为基础，在络合剂和富钠环境下通过共沉淀法，对锰基普鲁士蓝钠离子电池正极材料进行Fe2+掺杂研究，来提升其电化学性能。经过X射线衍射（XRD）、电子扫描显微镜（SEM）、X射线光电子能谱（XPS）检测和电化学测试表征。结果表明，在0.1 C电流密度下100圈循环后半电池的比容量为83.2 mA·h/g，容量保持率为69.3%。在倍率测试中比容量波动幅度不超过50%，5 C的大电流密度下保持61 mA·h/g的比容量，材料的改性明显提高了半电池的稳定性。
Abstract:
 Based on Prussian blue material with open frame structure, Fe2+ doping of manganese based Prussian blue sodium ion battery cathode material was studied by co-precipitation method under complexing agent and sodium rich environment, so as to improve its electrochemical performance. It was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) analysis and electrochemical test. The results show that the specific capacity of the second half of 100 cycles is 83.2 mA·h·g and the capacity retention rate is 69.3% at the current density of 0.1 C. In the rate test, the specific capacity fluctuation is less than 50%, and the specific capacity of 61 mA·h·g is maintained at a high current density of 5 C. The modification of the material significantly improves the stability of the half-cell.

参考文献/References:

[1] WU X Y, SHAO M M, WU C H, et al. Low defect FeFe-(CN)6 framework as stable host material for high performance Li-ion batteries[J]. ACS Applied Materials & Interfaces, 2016, 8(36): 23706-23712.
[2] DUNN B, KAMATH H, TARASCON J M. Electrical energy storage for the grid: a battery of choices[J]. Science, 2011, 334(6058): 928-935.
[3] 裘吕超,曾挺健,鲁旷达,等.用于钠离子正极的锰基普鲁士蓝材料的制备及其性能[J].材料科学与工程学报,2021,39(3):378-383.
[4] LIU J, XU Y G, KONG L B. Synthesis of polyvalention reaction of MoS2/CoS2-RGO anode materials forhigh-performance sodiumion batteries and sodium i-on capacitors[J]. Journal of Colloid and Interface Science, 2020, 575:42-53.
[5] YOU Y, YU X Q, YIN Y X, et al. Sodium iron hexacyanof-errate with high Na content as a Na-rich cathode material for Na-ion batteries[J]. Nano Research, 2015, 8 (1):117-128. 
[6] LIU Y, QIAO Y, ZHANG W Y, et al. Sodium storage in Na-rich NaxFeFe(CN)6 nanocubes[J]. Nano Energy, 2015, 12: 386-393.
[7] 万萍.钠离子电池普鲁士蓝类似物电极材料的电化学性能研究[D]. 合肥：中国科学技术大学,2020.
[8] 王博,刘双宇,兰珍云,等.钠离子电池正极材料普鲁士蓝掺镍的第一性原理[J].材料科学与工程学报,2020,38(2):286-289.
[9] 靳晓诚.类普鲁士蓝钠离子电池正极材料的制备与改性研究[D].哈尔滨：哈尔滨工业大学,2018.
[10] JO I H, LEE S M, KIM H S, et al. Electrochemical properties of NaxMnFe(CN)6·zH2O synthesized in a Taylor-Couette reactor as a Na-ion battery cathode material[J]. Journal of Alloys and Compounds, 2017, 729:590-596. 
[11] XIE M, XU M, HUANG Y H, et al. Na2NixCo1-xFe(CN)6: A class of Prussian blue analogs with transition metalelements as cathode materials for sodium ion batteries[J]. El- ectrochemistry Communications, 2015, 59:91-94. 
[12] ZHU Y H, ZHANG Z, BAO J J, et al. Multi-metal doped high capacity and stable prussian blue analogue for sodium-ion batteries[J]. International Journal of Energy Research, 2020, 44(11):9205-9212. 
[13] 李慧,刘双宇,王晓,等.铁镍普鲁士蓝电极材料的制备及其储钠性能[J].稀有金属材料与工程,2019,48(11):3735-3739.
[14] 龙宣有,王捷,赵丽娜,等.络合剂对铁基普鲁士蓝结构及储钠性能的影响[J].储能科学与技术,2020,9(1):57-64.
[15] 姜巍,王二东,孙海,等.普鲁士蓝及其衍生物中的钴、铁对其作为锂离子电池正极时比容量的影响[J].储能科学与技术,2017,6(6):1280-1285.
[16] WU J P, SONG J, DAI K H, et al. Modification of transition-metal redox by interstitial water in hexac-yanometalate electrodes for sodium-ion batteries[J].Journal of the American Chemical Society, 2017, 139(50):18358-18364.

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备注/Memo

备注/Memo:
［收稿日期］ 2021-10-25
［第一作者］ 王 壮（1996-），男，湖北汉川人，湖北工业大学硕士研究生，研究方向为钠离子电池正极材料
［通信作者］ 张 威（1981-），男，湖北武汉人，湖北工业大学讲师，研究方向为能源光电子
更新日期/Last Update: 2022-08-29